Workshop #6 at the NSLS Users' Meeting

"In-situ Analyses in Environmental and Chemical Systems"

Location: Bldg. 555, Chemistry, Hamilton Room

Date: Wednesday, May 25, 2005

Organizers:
Dean Hesterberg (NC State-Soil Science) (dean_hesterberg@ncsu.edu)
Jeff Fitts (BNL, Environmental Sciences) (fitts@bnl.gov)

Description: Biogeochemical systems such as soils, sediments, and subsurface aquifers are open systems that never reach equilibrium. Influxes and effluxes of materials such as water and gases, changes in temperature, and a prevalence of biological activity in such systems produce constant changes in porewater chemistry, particle-water interfacial composition, and chemical properties such as redox potential and pH. Molecular level studies of chemical kinetics in such complex systems of environmental importance are increasingly employing synchrotron-based techniques such as x-ray and UV-visible absorption spectroscopy and diffraction. In-situ measurements probe kinetic processes operating over a range of time scales. This workshop will highlight some of the state-of-the-art approaches, techniques, and equipment used for studying reaction kinetics in the environmenal, chemical, and biological sciences. Our goal is to bring together experts from various fields of science to convey recent scientific developments in kinetic analyses, and to discuss prospects for future approaches.

Schedule:

9:00 a.m. Opening Remarks
9:15 a.m. Edward A. Stern, Univ. of Washington
"Dale Sayers and the Development of XAFS as a Local Structure Determination Technique"
10:05 a.m. Break
10:20 a.m. Donald Sparks, U. Delaware
"Kinetics of Chemical Reactions in Environmental Systems: Research Needs and Challenges"
11:10 a.m. Wolfgang Caliebe, NSLS
"Time Resolved X-ray Absorption Spectroscopy - Past, Present, Future"
12:00 noon Lunch
1:10 p.m. Mali Balasubramanian, APS
"Application of In-Situ XAFS: Structural Study of Li Intercalation in Battery Materials"
2:00 p.m. Sam Shaw, Oxford Univ.
"Small Angle X-ray Scattering Studies of the Nucleation and Growth of Iron Oxyhydroxides"
2:50 p.m. Break
3:05 p.m. John B. Parise, SUNY, Stony Brook
"Time Resolved Powder Scattering for Elucidation of Long Range and Local Structures"
3:55 p.m. Dr. James D. Martin, NC State Dept. of Chemistry
"Probing the Mechanism of Nucleation and Crystal Growth in Inorganic Networks"
4:45 p.m. Adjourn